Credit Sprint / Study guides / Organismal chemistry
Credit Sprint's Guide to Descriptive and Experimental Chemistry for CLEP® Chemistry
About 23% of the CLEP® examCLEP® Chemistry asks more about what substances look like and do, and about lab technique, than AP® Chemistry does. Expect questions on colors of ions, precipitates, gases and flame tests, the properties of the main groups, and standard laboratory procedures.
What you need to know
- Colors: Cu²⁺ is blue, MnO₄⁻ purple, Fe³⁺ yellow-brown, Ni²⁺ green, Cr₂O₇²⁻ orange. Most main-group ions are colorless.
- Common precipitates: AgCl is white, AgI yellow, PbI₂ yellow, Cu(OH)₂ blue, Fe(OH)₃ red-brown, BaSO₄ white.
- Gases: H₂ burns with a pop, O₂ relights a glowing splint, CO₂ turns limewater cloudy, NH₃ has a sharp smell and turns damp red litmus blue.
- Alkali metals react vigorously with water to give H₂ and a basic solution. Halogens get less reactive down the group: Cl₂ oxidizes Br⁻ and I⁻.
- Flame tests: Na gives yellow, K lilac, Li red, Cu blue-green, Ca orange-red.
- Lab technique: read a buret to 0.01 mL, titrate until the indicator changes, heat a hydrate to constant mass, and use a pipet for accurate volumes.
- Separation methods: filtration for solid–liquid, distillation for liquids with different boiling points, chromatography by polarity.
- Safety: add acid to water, wear goggles, use a fume hood for toxic gases.
Practice questions
1. A 5.00 g sample of hydrated copper(II) sulfate, CuSO₄·xH₂O, is heated until 3.19 g of anhydrous CuSO₄ (159.6 g/mol) remains. What is x?
- 1
- 3
- 5
- 10
Show answer
5. Water lost = 1.81 g = 0.100 mol; CuSO₄ = 0.0200 mol; ratio = 5.
2. Which technique is best for separating a mixture of two miscible liquids with different boiling points?
- Paper chromatography
- Magnetic separation
- Filtration
- Distillation
Show answer
Distillation. The lower-boiling liquid vaporizes first and is condensed.
3. UV-visible spectroscopy is used to determine the concentration of a colored solution because
- the absorbance at a chosen wavelength is proportional to concentration
- absorbance is independent of concentration
- the solution emits light proportional to its mass
- colored solutions don't absorb light
Show answer
the absorbance at a chosen wavelength is proportional to concentration. This is Beer's law.
4. In paper chromatography, the solvent front travels 8.0 cm and a spot travels 2.0 cm. What is its Rf?
- 4.0
- 6.0
- 0.25
- 0.75
Show answer
0.25. Rf = 2.0 ÷ 8.0 = 0.25.
5. In paper chromatography with a polar paper and a nonpolar solvent, the more polar component
- travels a shorter distance
- travels farther
- dissolves in the paper
- does not move at all in any case
Show answer
travels a shorter distance. It is attracted more strongly to the paper.
6. Excess NaCl solution is added to 50.0 mL of 0.100 M AgNO₃. What mass of AgCl (143.3 g/mol) precipitates?
- 0.00500 g
- 14.3 g
- 0.717 g
- 7.17 g
Show answer
0.717 g. 0.00500 mol × 143.3 g/mol = 0.717 g.