Credit Sprint / Study guides / Organismal chemistry

Credit Sprint's Guide to Descriptive and Experimental Chemistry for CLEP® Chemistry

About 23% of the CLEP® exam

CLEP® Chemistry asks more about what substances look like and do, and about lab technique, than AP® Chemistry does. Expect questions on colors of ions, precipitates, gases and flame tests, the properties of the main groups, and standard laboratory procedures.

Periodic trends left → right: IE ↑, electronegativity ↑, radius ↓ top → bottom: radius ↑, IE ↓ Most reactive nonmetal: F (top right)Most reactive metal: Cs / Fr (bottom left)

What you need to know

  • Colors: Cu²⁺ is blue, MnO₄⁻ purple, Fe³⁺ yellow-brown, Ni²⁺ green, Cr₂O₇²⁻ orange. Most main-group ions are colorless.
  • Common precipitates: AgCl is white, AgI yellow, PbI₂ yellow, Cu(OH)₂ blue, Fe(OH)₃ red-brown, BaSO₄ white.
  • Gases: H₂ burns with a pop, O₂ relights a glowing splint, CO₂ turns limewater cloudy, NH₃ has a sharp smell and turns damp red litmus blue.
  • Alkali metals react vigorously with water to give H₂ and a basic solution. Halogens get less reactive down the group: Cl₂ oxidizes Br⁻ and I⁻.
  • Flame tests: Na gives yellow, K lilac, Li red, Cu blue-green, Ca orange-red.
  • Lab technique: read a buret to 0.01 mL, titrate until the indicator changes, heat a hydrate to constant mass, and use a pipet for accurate volumes.
  • Separation methods: filtration for solid–liquid, distillation for liquids with different boiling points, chromatography by polarity.
  • Safety: add acid to water, wear goggles, use a fume hood for toxic gases.

Practice questions

1. A 5.00 g sample of hydrated copper(II) sulfate, CuSO₄·xH₂O, is heated until 3.19 g of anhydrous CuSO₄ (159.6 g/mol) remains. What is x?
  1. 1
  2. 3
  3. 5
  4. 10
Show answer

5. Water lost = 1.81 g = 0.100 mol; CuSO₄ = 0.0200 mol; ratio = 5.

2. Which technique is best for separating a mixture of two miscible liquids with different boiling points?
  1. Paper chromatography
  2. Magnetic separation
  3. Filtration
  4. Distillation
Show answer

Distillation. The lower-boiling liquid vaporizes first and is condensed.

3. UV-visible spectroscopy is used to determine the concentration of a colored solution because
  1. the absorbance at a chosen wavelength is proportional to concentration
  2. absorbance is independent of concentration
  3. the solution emits light proportional to its mass
  4. colored solutions don't absorb light
Show answer

the absorbance at a chosen wavelength is proportional to concentration. This is Beer's law.

4. In paper chromatography, the solvent front travels 8.0 cm and a spot travels 2.0 cm. What is its Rf?
  1. 4.0
  2. 6.0
  3. 0.25
  4. 0.75
Show answer

0.25. Rf = 2.0 ÷ 8.0 = 0.25.

5. In paper chromatography with a polar paper and a nonpolar solvent, the more polar component
  1. travels a shorter distance
  2. travels farther
  3. dissolves in the paper
  4. does not move at all in any case
Show answer

travels a shorter distance. It is attracted more strongly to the paper.

6. Excess NaCl solution is added to 50.0 mL of 0.100 M AgNO₃. What mass of AgCl (143.3 g/mol) precipitates?
  1. 0.00500 g
  2. 14.3 g
  3. 0.717 g
  4. 7.17 g
Show answer

0.717 g. 0.00500 mol × 143.3 g/mol = 0.717 g.